Identify chemical hazards and incompatibilities of hypochlorite compounds
Implement proper storage, handling, and dilution procedures
Select and use appropriate PPE for hypochlorite operations
Respond effectively to chemical exposures and emergency situations
Monitor workplace conditions and recognize exposure symptoms
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OSHA sets the Permissible Exposure Limit (PEL) for chlorine gas at 1 part per million (ppm) as a ceiling limit, meaning this concentration should never be exceeded, not even momentarily. Most people can smell chlorine at 0.3 ppm, well below the danger level.
Store sodium hypochlorite in cool (below 70°F), dry, well-ventilated areas away from direct sunlight. Keep it segregated from acids, ammonia, and organic materials by at least 20 feet or physical barriers. Use only HDPE or polypropylene containers, never metal. The chemical degrades over time, losing approximately 20% strength per year.
Immediately flush eyes with lukewarm water for at least 15 minutes, holding eyelids open to ensure thorough rinsing. Remove contact lenses if possible, but don't delay flushing to do so. Seek medical evaluation even for minor exposures, as delayed effects can occur.
Mixing hypochlorite with acids (including vinegar) produces chlorine gas, which can cause severe respiratory damage or death. Mixing with ammonia creates chloramine vapors, which are equally toxic and potentially explosive. Never mix hypochlorite with any other chemical unless specifically directed by manufacturer instructions.
Water treatment facilities use bulk quantities for disinfection. Healthcare facilities use specific concentrations for surface disinfection and instrument processing. Food processors use FDA-approved concentrations (50-200 ppm) as no-rinse sanitizers. Swimming pools use calcium hypochlorite for water treatment. Each industry requires specific safety protocols based on concentration, volume, and application method.
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